C–C Bond Forming Reductive Elimination from Diarylplatinum Complexes Driven by Visible-Light-Mediated Photoredox Reactions
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https://figshare.com/articles/dataset/C_C_Bond_Forming_Reductive_Elimination_from_Diarylplatinum_Complexes_Driven_by_Visible_Light_Mediated_Photoredox_Reactions/2118172
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资源简介：
A series
of dinuclear Pt(II) bis-aryl complexes with visible-light-absorbing
Ir(III)–cyclometalate units were synthesized, and their molecular
structure and photophysical and electrochemical properties were investigated.
The dinuclear complexes underwent reductive elimination upon visible-light
irradiation at ambient temperature to afford the corresponding biaryls.
The photoredox process at the Ir center induces the oxidation of the
Pt(II)–Ar2 center to [Pt–Ar2](III) to accelerate reductive elimination.
创建时间：
2016-02-12
