Data to support study of Structural Bifurcation in the High→Low-Spin and Low→High-Spin Phase Transitions Explains the Asymmetric Spin-Crossover in [FeL2][BF4]2 (L = 2,6-Di{pyrazol-1-yl}isonicotinonitrile). [Dataset]
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https://archive.researchdata.leeds.ac.uk/1351/
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资源简介：
The title compound exhibits a spin-transition with asymmetric thermal hysteresis. It crystallises as two high-spin polymorphs HS1 and HS2, which convert to the low-spin phases LS3 and LS4 at low temperatures. The HS1 fraction increases at the expense of HS2 upon repeated scanning, which reflects that LS4 converts to a mixture of HS1 and HS2 on rewarming.
提供机构：
University of Leeds
创建时间：
2024-12-13
