New Lithium Ion Clusters for Construction of Porous MOFs
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Two novel types of lithium clusters, Li4 tetramer and Li2 dimer, have been created as the building blocks of MOFs. The assembly of such unprecedented clusters with two types of tricarboxylate ligands leads to two highly open frameworks, one of which exhibits a very high CO2 uptake capacity among Li-based MOFs. The work reveals the interesting and unprecedented structural chemistry of lithium ions.
创建时间：
2016-02-18
