Synthesis of Neplanocin A and Its 3′-Epimer via an Intramolecular Baylis–Hillman Reaction
收藏NIAID Data Ecosystem2026-03-08 收录
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The key cyclopentenyl intermediate 11b was synthesized in 4 steps from d-ribose in 41% overall yield via an efficient intramolecular Baylis–Hillman reaction. This novel key intermediate can be modified easily and transformed to neplanocin A (1a) and its 3′-epimer (1b).
创建时间：
2016-02-16
