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Reactivity Studies of Heteroleptic Silylenes with N<sub>2</sub>O

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NIAID Data Ecosystem2026-03-09 收录
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Reaction of heteroleptic silylenes LSiX (L = PhC­(NtBu)2; X = PPh2 (1), NPh2 (2), NMe2 (3), OtBu (4)) with N2O resulted in the oxidized dimeric product [LSi­(X)­(μ-O)]2 (X = PPh2 (5), NPh2 (6), NMe2 (7), OtBu (8)), which contains a four-membered Si2O2 ring. Compounds 5–8 were characterized by spectroscopic and spectrometric techniques. The molecular structures of 5–8 were established by single-crystal X-ray structure analysis.

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2016-02-20
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