Ambient-Temperature Spin-State Switching Achieved by Protonation of the Amino Group in [Fe(H2Bpz2)2(bipy-NH2)]

Figshare2016-08-09 更新2026-04-29 收录

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https://figshare.com/articles/dataset/Ambient-Temperature_Spin-State_Switching_Achieved_by_Protonation_of_the_Amino_Group_in_Fe_H_sub_2_sub_Bpz_sub_2_sub_sub_2_sub_bipy-NH_sub_2_sub_/3505226

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Magnetism of a complex [Fe(H2Bpz2)2(bipy-NH2)] (H2Bpz2 = dihydrobis(1-pyrazolyl)borate, bipy-NH2 = 4,4′-diamino-2,2′-bipyridine) has been altered from paramagnetic to spin-crossover (SCO) behavior, through protonation of one amino group of bipy-NH2 with CF3SO3H. Complete SCO transition, both in solid state and in solution, occurs at ambient temperature.

创建时间：

2016-08-09