Table 2 1 H in Sesquiterpenoids and their quaternary ammonium hybrids from the mycelium of mushroom Stereum hirsutum by medium optimization

Table 2 1 H- (600 MHz) and 13 C-NMR (150 MHz) data for compounds 3 5 (δ in ppm, J in – Hz).
Position345δ H (mult,δ Cδ Hδ Cδ H (mult, J inδ CJ in Hz)(mult, JHz)in Hz)16.98,155.5,6.98,155.5,6.94, d (2.6)155.7,d (2.6)dbrd (5.5)dd2–46.9, s46.9, s–46.9, s32.06, dd40.5, t2.06, m40.5, t2.11, dd40.5, t(8.3,(8.3, 13.7)13.2)2.16, dd2.15, m2.00, dd(8.3,(8.3, 13.7)13.3)43.78, dt53.8, d3.78, m53.8, d3.68, td (2.6,53.7, d(2.6, 8.3)8.4)5–73.8, s–74.1, s–74.0, s6–171.3,–171.2,–171.2,sss7–131.9,–132.0,–131.5,sss8–181.5,–181.4,–181.2,sss9–137.6,–137.5,–137.4,sss101.31, s28.5, q1.30, s28.5, d1.27, s28.5, q111.22, s27.5, q1.21, s27.5, d1.19, s27.5, q121.35, s25.1, q1.34, s25.1, d1.23, s25.1, q138.38,125.2,8.39,125.2,8.27, d (6.5)124.9,d (6.3)dbrd (6.5)dd149.08,148.3,9.09,148.3,9.00, d (6.5)148.5,d (6.3)dbrd (6.5)dd159.25, s145.6,9.26, s145.6,9.09, s145.6,ddd1′–171.5,–171.3,–171.3,sss2′5.34, dd77.1, d5.32, m76.9, d5.60, m78.6, d(5.2, 9.5)3′2.80, m30.2, t2.81, m29.7, t3.89, m40.5, t2.48, m2.53, m3.52, m4′2.41, m32.6, t2.47, m31.9, t–137.3,s5′–176.4,–173.8,7.12–7.20,129.8,ssmd6′––4.01, t65.7, t130.0,(6.6)d7′––1.58, m31.7, t128.5,d8′––1.36, q20.2, t130.0,(7.5)d9′––0.92, t14.0, q129.8,(7.5)d