Journey from Mo−Mo Quadruple Bonds to Quintuple Bonds
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Journey from Mo−Mo Quadruple Bonds to Quintuple Bonds
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2009-09-09
相关数据集
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A series of compounds has been made containing quadruply bonded Re2(hpp)4X2 species (hpp = the anion of 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2a]pyrimidine), where X is CF3SO3 (1), CF3CO2 (2), and F (3)
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Pushing the Limits of Delta Bonding in Metal–Chromium Complexes with Redox Changes and Metal Swapping
Into the metalloligand Cr[N(o-(NCH2P(iPr)2)C6H4)3] (1, CrL) was inserted a second chromium atom to generate the dichromium complex Cr2L (2), which is a homobimetallic analogue of the known MCrL co
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Chemically Reversible Four-Electron Oxidation and Reduction Utilizing Two Inorganic Functional Groups
Four-electron oxidation of the quadruply bonded W2(II,II) compound W2(2,2′-dipyridylamide)4, 1, results in the formation of a novel, diamagnetic ditungsten terminal oxo compound [W2O(2,2′-dipyridylami
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Substituent Effects in Formally Quintuple-Bonded ArCrCrAr Compounds (Ar = Terphenyl) and Related Species
The effects of different terphenyl ligand substituents on the quintuple Cr−Cr bonding in arylchromium(I) dimers stabilized by bulky terphenyl ligands (Ar) were investigated. A series of complexes, ArC
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A series of formally triply bonded diplumbyne analogues of alkynes of the general formula ArPbPbAr (Ar = terphenyl ligand with different steric properties) was synthesized by two routes. All diplumbyn
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