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Hydroxyl-Directed Stereoselective Diboration of Alkenes

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NIAID Data Ecosystem2026-03-09 收录
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An alkoxide-catalyzed directed diboration of alkenyl alcohols is described. This reaction occurs in a stereoselective fashion and is demonstrated with cyclic and acyclic homoallylic and bishomoallylic alcohol substrates. After oxidation, the reaction generates 1,2-diols such that the process represents a method for the stereoselective directed dihydroxylation of alkenes.

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2015-12-17
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