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Unprecedented Marriage of a Cationic Pentanuclear Cluster and a 2D Polymeric Anionic Layer Based on a Flexible Tripodal Ligand and a Cu<sup>II</sup> Ion

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NIAID Data Ecosystem2026-03-06 收录
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The anionic CdI2-type topological net, [Cu2(tci)2]2−, and the pentanuclear copper cluster cation [Cu5(tci)2(OH)2(H2O)8]2+ [tci = tris(2-carboxyethyl)isocyanurate] form a complementary 3D supramolecular framework. Interestingly, there exist centrosymmetric cyclic (H2O)18 clusters in the cavities.

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2010-02-01
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