Enantioselective C–H Bond Addition of Pyridines to Alkenes Catalyzed by Chiral Half-Sandwich Rare-Earth Complexes
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https://figshare.com/articles/dataset/Enantioselective_C_H_Bond_Addition_of_Pyridines_to_Alkenes_Catalyzed_by_Chiral_Half_Sandwich_Rare_Earth_Complexes/2258797
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资源简介:
Cationic half-sandwich scandium alkyl
complexes bearing monocyclopentadienyl
ligands embedded in chiral binaphthyl backbones act as excellent catalysts
for the enantioselective C–H bond addition of pyridines to
various 1-alkenes, leading to formation of a variety of enantioenriched
alkylated pyridine derivatives in high yields and excellent enantioselectivity
(up to 98:2 er).
创建时间:
2016-02-16



