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Enantioselective C–H Bond Addition of Pyridines to Alkenes Catalyzed by Chiral Half-Sandwich Rare-Earth Complexes

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NIAID Data Ecosystem2026-03-08 收录
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https://figshare.com/articles/dataset/Enantioselective_C_H_Bond_Addition_of_Pyridines_to_Alkenes_Catalyzed_by_Chiral_Half_Sandwich_Rare_Earth_Complexes/2258797
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资源简介:
Cationic half-sandwich scandium alkyl complexes bearing monocyclopentadienyl ligands embedded in chiral binaphthyl backbones act as excellent catalysts for the enantioselective C–H bond addition of pyridines to various 1-alkenes, leading to formation of a variety of enantioenriched alkylated pyridine derivatives in high yields and excellent enantioselectivity (up to 98:2 er).
创建时间:
2016-02-16
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