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Hang-gliding with Ferrocenes: Unusual Coordination Chemistry of 1,1‘-Bis(mesitylthio)ferrocene

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NIAID Data Ecosystem2026-03-06 收录
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A rare C,S-cyclometalated PtIV complex is one of a series of transition metal complexes formed by the new redox-active and sterically hindered ligand 1,1‘-bis(mesitylthio)ferrocene. Simple PdII and PtII chelate species can be synthesized by less forcing reaction conditions, in addition to a Re2(CO)6Br2 dinuclear species featuring the ferrocene ligand adopting a binucleating role and forming an unusual “quasi-closed” bridged structure.

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2016-08-26
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