Formation of Functionalized 2H‑Azirines through PhIO-Mediated Trifluoroethoxylation and Azirination of Enamines
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A variety of enaminones and enamine carboxylic esters were converted to trifluoroethoxylated 2H-azirines through reactions with PhIO in trifluoroethanol (TFE). The cascade reaction is postulated to proceed via a PhIO-mediated oxidative trifluoroethoxylation and a subsequent azirination of the α-trifluoroethoxylated enamine intermediates.
创建时间：
2016-02-18
