Table 1 13 C in Determination of phenolic profiles of Herniaria polygama and Herniaria incana fractions and their in vitro antioxidant and anti-inflammatory effects

Table 1 13 C NMR (125 MHz) and 1 H NMR (500 MHz) data for compound 54 (δ in ppm; J in Hz; measured in MeOH- d; 30 ◦ C). 4 PositionTypeδCδHRhamnocitrin2C159.33C134.54C179.35C162.96CH99.16.33, d (2.3)7C167.28CH93.16.61, d (2.3)9C158.410C106.81′C123.02′CH132.28.05, d (8.8)3′CH116.26.90, d (8.8)4′C161.55′CH116.26.90, d (8.8)6′CH132.28.05, d (8.8)7- O -MeCH356.53.89, s3- O -Glc p1′′CH100.35.65, d (7.5)2′′CH80.03.63, dd (9.0, 7.5)3′′′′CH78.83.55, t (9.0)4′′CH71.73.31, t (9.0)5′′CH75.53.40 a6′′CH264.24.23, d (11.7)4.06, dd (11.7, 5.9)Rha p1′′′CH102.75.24, d (1.8)2′′′CH72.44.01, dd (3.5, 1.8)3′′′CH72.33.79, dd (9.3, 3.5)4′′′CH74.13.36, t (9.3)5′′′CH69.94.07, dq (9.3, 6.2)6′′′CH317.61.01 d (6.2)HMG1′′′′C172.22′′′′CH246.02.38–2.41 (2H, m) a3′′′′C70.64′′′′CH246.02.42, d (15.1)2.34, d (15.1)5′′′′C174.53′′′′-MeCH327.61.14, s a Overlapped with other signals.