Iron Complexes with Stabilized Germylenes: Syntheses and Characterizations
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https://figshare.com/articles/dataset/Iron_Complexes_with_Stabilized_Germylenes_Syntheses_and_Characterizations/2198512
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资源简介：
The
reactivity of amidinate (1a,b, 2a)- or NHC (5a,b)-stabilized germanium(II)
compounds toward diiron nonacarbonyl has been investigated. These
germylenes act as two-electron carbene-like ligands and lead to stable
germylene iron complexes by exchange reaction of a carbonyl ligand.
Whereas the amidinato chloro germylenes lead to stable complexes,
a bis(iron germylene) oxide was obtained from the bis-amidinato germylene.
The reactions of NHC-stabilized germylenes (5a,b) with Fe2(CO)9 were also explored,
giving donor–acceptor complexes of germylenes. All the germanium–iron
complexes were fully characterized (1H and 13C NMR and IR) including by single-crystal X-ray diffraction structure
determinations.
创建时间：
2016-02-14
