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Lewis Acids Promoted Formal Intramolecular [3 + 2] Parallel and Cross-Cycloadditions of Cyclopropane 1,1-Diesters with Allenes

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https://figshare.com/articles/dataset/Lewis_Acids_Promoted_Formal_Intramolecular_3_2_Parallel_and_Cross_Cycloadditions_of_Cyclopropane_1_1_Diesters_with_Allenes/2352877
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A novel Lewis acid promoted formal intramolecular [3 + 2] parallel/cross-cycloaddition of cyclopropane 1,1-diesters with allenes has been successfully developed, in which the two CC of allenes were involved respectively. This provides a general and efficient strategy for the construction of structurally diverse [4.3.0]nonane and [3.2.1]octane skeletons.
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2013-11-15
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