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Organocatalyzed Anion Relay Leading to Functionalized 2,3-Dihydrofurans

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Figshare2016-02-19 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Organocatalyzed_Anion_Relay_Leading_to_Functionalized_2_3_Dihydrofurans/2391733
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A DABCO-mediated organocatalyzed anion relay cascade based on 1-cinnamoylcyclopropanecarboxamides has been developed and applied in the construction of 2,3-dihydrofurans with the original alkene and amide functionalities intact. In the aza-oxy-carbanion relay process, DABCO provides both the electron source and sink. The enolate anion-triggered ring opening of the cyclopropane is ascribed to the key step in the anion relay cascade.
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2016-02-19
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