1,5-Rhodium Shift in Rearrangement of <i>N</i>‑Arenesulfonylazetidin-3-ols into Benzosultams

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https://figshare.com/articles/dataset/1_5_Rhodium_Shift_in_Rearrangement_of_i_N_i_Arenesulfonylazetidin_3_ols_into_Benzosultams/2338243

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Benzosultams are synthesized in an enantiopure form starting from α-amino acids through a rhodium-catalyzed rearrangement reaction of N-arenesulfonylazetidin-3-ols. Mechanistically, this reaction involves C–C bond cleavage by β-carbon elimination and C–H bond cleavage by a 1,5-rhodium shift.

创建时间：

2016-02-18