Ligandless, Anionic, Arylpalladium Halide Intermediates in the Heck Reaction

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https://figshare.com/articles/dataset/Ligandless_Anionic_Arylpalladium_Halide_Intermediates_in_the_Heck_Reaction/2800654 数据链接链接失效反馈

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Ligandless, Anionic, Arylpalladium Halide Intermediates in the Heck Reaction

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2010-01-13

Mechanistic Significance of the Si–O–Pd Bond in the Palladium-Catalyzed Cross-Coupling Reactions of Arylsilanolates

交叉偶联反应

钯催化中间体

Through the combination of reaction kinetics (both stoichiometric and catalytic), solution- and solid-state characterization of arylpalladium(II) arylsilanolates, and computational analysis, the i

NIAID Data Ecosystem50

Low-Temperature Heck Reactions of Axially Chiral o -Iodoacrylanilides Occur with Chirality Transfer: Implications for Catalytic Asymmetric Heck Reactions

不对称催化

Heck反应机理

Low-temperature Heck reactions of chiral o-iodoacrylanilides with achiral palladium catalysts occur with efficient transfer of chirality from the chiral axis of the precursor to the new stereocenter o

NIAID Data Ecosystem30

Ligandless, Anionic, Arylpalladium Halide Intermediates in the Heck Reaction

Heck反应机理

有机金属中间体

Ligandless, Anionic, Arylpalladium Halide Intermediates in the Heck Reaction

NIAID Data Ecosystem20

Palladium-Catalyzed Regiocontrollable Reductive Heck Reaction of Unactivated Aliphatic Alkenes

催化有机合成

Heck反应机理

A general Pd-catalyzed intermolecular reductive Heck reaction of both terminal and internal unactivated aliphatic alkenes has been first developed. This method affords γ- and δ-arylated alkyl carboxyl

NIAID Data Ecosystem30

On the Mechanism of the Palladium(II)-Catalyzed Decarboxylative Olefination of Arene Carboxylic Acids. Crystallographic Characterization of Non-Phosphine Palladium(II) Intermediates and Observation of Their Stepwise Transformation in Heck-like Processes

钯催化脱羧烯基化

Heck反应机理

Mechanistic studies of a palladium-mediated decarboxylative olefination of arene carboxylic acids are presented, providing spectroscopic and, in two instances, crystallographic evidence for intermedia

NIAID Data Ecosystem30

Ligandless, Anionic, Arylpalladium Halide Intermediates in the Heck Reaction

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