Oxidation of Tetraphenylhexaazaanthracene: Accessing a Scissor Dimer of a 16π Biscyanine
收藏NIAID Data Ecosystem2026-03-09 收录
下载链接：
https://figshare.com/articles/dataset/Oxidation_of_Tetraphenyl_hexaaza_anthracene_Accessing_a_Scissor_Dimer_of_a_16_Biscyanine/2085088
下载链接
链接失效反馈官方服务：
资源简介：
Tetraphenylhexaazaanthracene
(TPHA), a fluorescent
zwitterionic biscyanine with a closed-shell singlet ground state,
on treatment with manganese dioxide or phenyliodine bis(trifluoroacetate)
(PIFA), undergoes oxidative dimerization to give a near-zero
dipole scissor 5,5′-dimer DI-TPHA. Both acene
components of the new dimer DI-TPHA maintain their biscyanine
closed-shell singlet ground state motifs, as judged by analysis of
both single crystal X-ray crystallographic and density functional
theory computational studies; however, unlike TPHA, DI-TPHA is only very weakly fluorescent.
创建时间：
2016-02-11
