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Ligand-Based Reduction of CO2 and Release of CO on Iron(II)

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Figshare2016-02-20 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Ligand_Based_Reduction_of_CO_sub_2_sub_and_Release_of_CO_on_Iron_II_/2491831
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A synthetic cycle for the CO2-to-CO conversion (with subsequent release of CO) based on iron­(II), a redox-active pydridinediimine ligand (PDI), and an O-atom acceptor is reported. This conversion is a passive-type ligand-based reduction, where the electrons for the CO2 conversion are supplied by the reduced PDI ligand and the ferrous state of the iron is conserved.
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2016-02-20
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