Asymmetric Synthesis of the Chlorocyclopropane-Containing Callipeltoside A Side Chain
收藏NIAID Data Ecosystem2026-03-06 收录
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The callipeltoside A chlorocyclopropyl-containing dienyne side chain has been synthesized in nine steps and 33% overall yield from commercially available 1,2,5,6-O-dicyclohexylidene-d-mannitol. The key steps in the synthesis are a highly diastereoselective cyclopropanation of a vinyl chloride allylic ether and a Suzuki cross-coupling to complete the carbon framework.
创建时间：
2016-08-20
