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Chemistry of Boryllithium: Synthesis, Structure, and Reactivity

NIAID Data Ecosystem2026-03-06 收录

硼化学

硼基锂反应性

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https://figshare.com/articles/dataset/Chemistry_of_Boryllithium_Synthesis_Structure_and_Reactivity/2843548 数据链接链接失效反馈

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Chemistry of Boryllithium: Synthesis, Structure, and Reactivity

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创建时间：

2016-02-26

硼化学

氮氧化物反应

The electrophilic pentafluoroarylboranes B(C6F5)3, PhB(C6F5)2, and ClB(C6F5)2 react with (trimethylsilyl)diazomethane, diphenyldiazomethane, or (pentafluorophenyl)diazomethane, affording insertio

NIAID Data Ecosystem30

An Air-Stable Organoboron Compound, Dithienooxadiborepine: Preparation and Functionalization

硼化学

π共轭体系

π-Conjugated organoboron molecules, which are easy to prepare, stable against moisture, and easy to functionalize, are scarce. Here, we report a one-pot synthesis of an air-stable organoboron compound

NIAID Data Ecosystem20

Isomeric Dipyrrinato and Dipyrromethanato Boranes

硼化学

反应机理

Reaction of the dipyrrin ligand 1,3,7,9-tetramethyl-2,8-diethyldipyrrin with BH3·SMe2 initially gives a dipyrrin-BH3 adduct, which eliminates dihydrogen to form the dipyrrin-supported BH2 borane LHBH2

NIAID Data Ecosystem20

A B−B Bond-Containing Polycyclic π-Electron System: Dithieno-1,2-dihydro-1,2-diborin and Its Dianion

硼化学

共轭分子合成

A B−B Bond-Containing Polycyclic π-Electron System: Dithieno-1,2-dihydro-1,2-diborin and Its Dianion

NIAID Data Ecosystem30

Directed, Palladium(II)-Catalyzed Enantioselective anti- Carboboration of Alkenyl Carbonyl Compounds

催化不对称合成

硼化学

A substrate-directed enantioselective anti-carboboration reaction of alkenes has been developed, wherein a carbon-based nucleophile and a boron moiety are installed across the CC bond through a five-

NIAID Data Ecosystem20

Chemistry of Boryllithium: Synthesis, Structure, and Reactivity

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