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An Accurately-Constructed Structural Model for an Active Site of Fe-Containing Superoxide Dismutases (Fe-SODs)

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https://figshare.com/articles/dataset/An_Accurately_Constructed_Structural_Model_for_an_Active_Site_of_Fe_Containing_Superoxide_Dismutases_Fe_SODs_/3358132
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资源简介:
A novel structural model, [Fe(bpga)(N3)(OCH3)] (1) (BPGA:  bis(6-pivalamido-2-pyridylmethyl)(carboxy-methyl)amine), for an active site of Fe-containing SOD enzyme with N3- has been accurately designed and prepared, which has been characterized by X-ray structure analysis and UV−vis, ESR, and IR spectroscopies. Reaction of 1 with acid/base in methanol has shown that the superoxide-accessible site is the N3--coordination site in the equatorial plane.
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2003-12-01
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