Enantioselective Aminomethylamination of Conjugated Dienes with Aminals Enabled by Chiral Palladium Complex-Catalyzed C–N Bond Activation
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https://figshare.com/articles/dataset/Enantioselective_Aminomethylamination_of_Conjugated_Dienes_with_Aminals_Enabled_by_Chiral_Palladium_Complex_Catalyzed_C_N_Bond_Activation/3123523
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资源简介：
A novel
highly enantioselective aminomethylamination of conjugated dienes
with aminals catalyzed by a chiral palladium complex ligated with
BINOL-derived chiral diphosphinite has been successfully developed.
This reaction proceeds via a Pd-catalyzed cascade C–N bond
activation, aminomethylation, and asymmetric allylic amination reaction
under mild reaction conditions, providing a unique and efficient strategy
for the synthesis of enantiomerically pure allylic 1,3-diamines.
创建时间：
2016-03-31
