Azide Addition to an Endohedral Metallofullerene: Formation of Azafulleroids of Sc<sub>3</sub>N@<i>I</i><sub><i>h</i></sub>-C<sub>80</sub>
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The reaction of an organic azide with an endohedral metallofullerene has been investigated for the first time. Isomeric [5,6]- and [6,6]-azafulleroids can be obtained from the thermal reaction of Sc3N@Ih-C80 with 4-isopropoxyphenyl azide, while photoirradiation leads exclusively to the [6,6]-azafulleroid. An unprecedented thermal interconversion between the two isomeric azafulleroids has also been discovered.
创建时间：
2016-02-20
