Direct Catalytic Asymmetric Mannich-Type Reaction of α‑Sulfanyl Lactones
收藏Figshare2016-02-19 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Direct_Catalytic_Asymmetric_Mannich_Type_Reaction_of_Sulfanyl_Lactones/2408023
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Catalytic asymmetric Mannich-type reactions of α-sulfanyl lactones to aldimines were promoted by a chiral Ag complex/DBU binary catalyst. The reaction proceeded in a syn-selective manner in high enantioselectivity. Alkylative activation of the sulfide of the Mannich adduct allowed for the formation of trisubstituted aziridines.
创建时间：
2016-02-19
