Stereoselective Intermolecular [2 + 2] Cycloadditions of Erlenmeyer–Plöchl Azlactones Using Visible Light Photoredox Catalysis
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https://figshare.com/articles/dataset/Stereoselective_Intermolecular_2_2_Cycloadditions_of_Erlenmeyer_Plo_chl_Azlactones_Using_Visible_Light_Photoredox_Catalysis/7403525
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资源简介：
The first report of the preparation
of symmetric and nonsymmetric
diaminotruxinic derivatives through the photoredox [2 + 2] cycloadditions
of Erlenmeyer azlactones is described, affording the desired compounds
in high regio- and diastereocontrol (only head-to-head coupling).
Mechanistic studies by DFT suggest that the reaction proceeds through
a neutral photocatalytic pathway.
创建时间：
2018-11-29
