A Domino Ring-Opening/Epoxidation of 1,2-Dioxines
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https://figshare.com/articles/dataset/A_Domino_Ring_Opening_Epoxidation_of_1_2_Dioxines/3344131
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资源简介：
When allowed to react with alkaline hydrogen
peroxide, monocyclic 1,2-dioxines ring-open to their isomeric
γ-hydroxyenone intermediates which are rapidly epoxidized
to afford trans-4-hydroxy-2,3-epoxyketones in 21−81% yield.
In the case of meso-1,2-dioxines, Co(II) complex catalyzed
asymmetric ring-opening of the 1,2-dioxine may be employed
to furnish enantioenriched epoxides
创建时间：
2016-05-07
