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Assembly of Four Kinds of Cages into Porous Metal–Organic Framework for Selective Sorption of Light Hydrocarbons

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NIAID Data Ecosystem2026-03-09 收录
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The direct assembly of four kinds of cages by face-sharing and edge-sharing modes with Zn3(μ3-OH–)­(H2O)­(COO–)4 units and organic ligands generates a porous framework material including 3D channels, which shows high adsorption enthalpy of C3H8 (35 kJ/mol) and excellent adsorption selectivity of C3H8 over CH4 under ambient conditions.

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2016-02-16
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