Highly <i>cis</i>-Selective Cyclopropanations with Ethyl Diazoacetate Using a Novel Rh(I) Catalyst with a Chelating N-Heterocyclic Iminocarbene Ligand
收藏NIAID Data Ecosystem2026-03-06 收录
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资源简介：
A structurally characterized Rh(I) iminocarbene complex (N,C)Rh(CO)Cl is activated with AgOTf to act as a highly cis-selective catalyst for the cyclopropanation of substituted styrenes and other alkenes with ethyl diazoacetate (11 examples, 10−99% yield, up to >99% cis-selectivity).
创建时间：
2009-02-05
