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Reactions of Boratabenzene Yttrium Complexes with KN(SiMe<sub>3</sub>)<sub>2</sub>: Salt Elimination and π-Ligand Displacement

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NIAID Data Ecosystem2026-03-06 收录
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Several solvent-free boratabenzene yttrium chlorides were synthesized and structurally characterized. Their reactions with KN(SiMe3)2 first gave boratabenzene yttrium amides; the latter reacted further with KN(SiMe3)2, which results in π-ligand displacement. The boratabenzene yttrium amides showed good catalytic activities for intramolecular hydroamination.

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2016-02-26
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