Structure Determination of Neptunium(VI) μ<sub>3</sub>-Hydroxobenzoate, [(NpO<sub>2</sub>)<sub>2</sub>(μ<sub>3</sub>-OH)<sub>2</sub>(H<sub>5</sub>C<sub>6</sub>COO)<sub>2</sub>]·2H<sub>2</sub>O
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Neptunium(VI) benzoate with μ3-OH− has been isolated and studied by the X-ray method. The main structural motive in the crystal is corrugated ribbons [(NpO2)2(μ3-OH)2(C7H5O2)2]n extended along the c axes in which three neptunium pentagonal bipyramids are linked through the μ3-OH− ligand. The benzoate ions are arranged at both sides of the ribbons, and each anion binds two adjacent NpO2. The water molecules are arranged in the channels along the c axis.
创建时间:
2016-02-24



