Hydrothermal Synthesis of a Novel Uranium Oxalate/Glycolate via In-Situ Ligand Formation
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https://figshare.com/articles/dataset/Hydrothermal_Synthesis_of_a_Novel_Uranium_Oxalate_Glycolate_via_In_Situ_Ligand_Formation/2992579
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资源简介：
A novel templated uranium oxalate/glycolate, (UO2)4(O)2(C2O4)(H2C2O3)2·2[(C8H20)N] (a = 7.9230(8) Å, b = 13.3793(13) Å, c = 17.4141(18) Å, β = 96.006(2)°, monoclinic, P21/n, Z = 2), has been synthesized under hydrothermal
conditions via in-situ ligand synthesis. The oxalate and glycolate anions have been formed through the oxidation
of 1,4-diazabicyclo[2.2.2]octane, which proceeds through intermediates such as piperazine and ethylene glycol.
Reported herein is the synthesis of this compound, crystal structure, and mechanistic information regarding the
oxidation pathway.
创建时间：
2016-06-03
