Synthesis of the Elusive (R<sub>3</sub>P)<sub>2</sub>MF<sub>2</sub> (M = Pd, Pt) Complexes
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The synthesis and characterization of previously unknown palladium(II) and platinum(II) difluoro phosphine complexes are described. These complexes can be obtained either via a halide metathesis reaction with AgF in dichloromethane or by reacting the corresponding dimethyl complexes with XeF2. While the Pt(II) complexes can be prepared with both aryl- and alkyl-phosphine ligands, the stability of the Pd(II) complexes is limited to those having cis-oriented trialkyl phosphine ligands.
创建时间:
2016-05-07



