Cyanide-Bridged W(V)−Mn(II) Bimetallic Double-Zigzag Chains with a Metamagnetic Nature
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A cyanide-bridged W−Mn bimetallic compound [W(CN)6(bpy)]2[Mn(H2O)2]·4H2O (1) (bpy = 2,2‘-bipyridine) with a one-dimensional, crossed double-zigzag chain structure was prepared by self-assembling [W(CN)6(bpy)]- and Mn2+ ions in a 2:1 reaction ratio. The magnetic properties of 1 exhibit a field-induced metamagnetic behavior.
创建时间：
2005-10-31
