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Direct meso-Alkynylation of Porphyrins Doubly Assisted by Pyridyl Coordination

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Figshare2016-02-20 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Direct_i_meso_i_Alkynylation_of_Porphyrins_Doubly_Assisted_by_Pyridyl_Coordination/2517997
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Direct meso-alkynylation of β,β′-dipyridylporphyrin with various alkynyllithium reagents has been achieved, in which the β,β′-dipyridyl groups play an important role in facilitating the nucleophilic addition of the reagents through double coordination. This method enabled the synthesis of a meso-ethynylene-bridged diporphyrin.
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2016-02-20
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