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Hexanuclear Platinum(II) Thiolate Macrocyclic Host: Charge-Transfer-Driven Inclusion of a AgI Ion Guest

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Figshare2016-09-13 更新2026-04-29 收录
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The inclusion of a AgI ion by a hexanuclear platinum­(II) thiolate macrocycle in solution was demonstrated, and the inclusion structure was determined by X-ray crystallography. Unique host–guest intermetallic interactions driven by charge transfer were elucidated by optical absorption spectroscopy and theoretical calculations.

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2016-09-13
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