遇见数据集

Tetraquinanes via [4 + 4] Photocycloaddition/Transannular Ring Closure

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NIAID Data Ecosystem2026-03-06 收录
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Intramolecular [4 + 4] photocycloaddition of a furan and a cyclopentane-annulated 2-pyridone yields a cyclooctadiene product with four new stereogenic centers. Transannular ring closure produces the 5−5−5−5 fused ring system of the crinipellins, including three contiguous quaternary carbons, with the correct absolute stereochemistry derived from (−)-carvone.

创建时间:
2016-02-24
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