Catalytic Four-Electron Reduction of O2 via Rate-Determining Proton-Coupled Electron Transfer to a Dinuclear Cobalt-μ-1,2-peroxo Complex
收藏Figshare2016-02-20 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Catalytic_Four_Electron_Reduction_of_O_sub_2_sub_via_Rate_Determining_Proton_Coupled_Electron_Transfer_to_a_Dinuclear_Cobalt_1_2_peroxo_Complex/2512258
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资源简介：
Four-electron reduction of O2 by octamethylferrocene (Me8Fc) occurs efficiently with a dinuclear cobalt-μ-1,2-peroxo complex, 1, in the presence of trifluoroacetic acid in acetonitrile. Kinetic investigations of the overall catalytic reaction and each step in the catalytic cycle showed that proton-coupled electron transfer from Me8Fc to 1 is the rate-determining step in the catalytic cycle.
创建时间：
2016-02-20
