Catalytic Four-Electron Reduction of O2 via Rate-Determining Proton-Coupled Electron Transfer to a Dinuclear Cobalt-μ-1,2-peroxo Complex
收藏数据链接：
官方服务：
资源简介：
Four-electron reduction of O2 by octamethylferrocene (Me8Fc) occurs efficiently with a dinuclear cobalt-μ-1,2-peroxo complex, 1, in the presence of trifluoroacetic acid in acetonitrile. Kinetic investigations of the overall catalytic reaction and each step in the catalytic cycle showed that proton-coupled electron transfer from Me8Fc to 1 is the rate-determining step in the catalytic cycle.
创建时间：
2016-02-20
