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Rigid π‑Extended Triptycenes via a Hexaketone Precursor

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NIAID Data Ecosystem2026-03-08 收录
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A high-yielding synthesis of a rigid hexaketone is presented that can be transformed into π-extended D3h-symmetric triptycene derivatives with high internal molecular free volumes (IMFVs). The products show excellent photophysical properties combined with high specific surface areas.

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2014-02-07
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