1,2-Dihydro-1,2-oxaborine: A Boron−Oxygen Heterocycle Isoelectronic with Benzene
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1,2-Dihydro-2-phenyl-1,2-oxaborine (1b) has been prepared by the reaction of (2,3-dihydro-1,2-oxaborol-3-yl)potassium (8) with methylene chloride and KN(SiMe3)2. Structural characterization of the phenyl−Cr(CO)3 complex 9 suggests that the 1,2-dihydro-1,2-oxaborine ring has a π-delocalized structure.
创建时间：
2007-03-26
