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Carborane-Functionalized Polyaza Aromatic Ligands: Synthesis, Crystal Structure, and a Copper(II) Complex

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https://figshare.com/articles/dataset/Carborane_Functionalized_Polyaza_Aromatic_Ligands_Synthesis_Crystal_Structure_and_a_Copper_II_Complex/3077638
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资源简介:
A consecutive aromatic nucleophilic substitutions of hydrogen in 1,2,4-triazine 4-oxides and an aza Diels−Alder reaction is a versatile route to carborane-functionalized bi- and terpyridines and their 1,2,4-triazine analogues. The heterocycles facilitate deboronation of the substituted carboranes, and the carborane moiety has a significant influence on the coordination properties of the ligands as well.
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2016-03-01
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