Cyanide-Bridged Decanuclear Cobalt–Iron Cage
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https://figshare.com/articles/dataset/Cyanide_Bridged_Decanuclear_Cobalt_Iron_Cage/2282557
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资源简介:
A cyanide-bridged
decanuclear [Co6Fe4] cluster was synthesized
by a one-pot reaction, and the magnetic properties and electronic
configuration were investigated. The complex displayed thermally controlled
electron-transfer-coupled spin transition (ETCST) behavior between
CoIII low-spin–NC–FeII low-spin
and CoII high-spin–NC–FeIII low-spin
states, as confirmed by single-crystal X-ray, magnetic, and Mössbauer
analyses.
创建时间:
2014-06-16



