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Cyanide-Bridged Decanuclear Cobalt–Iron Cage

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https://figshare.com/articles/dataset/Cyanide_Bridged_Decanuclear_Cobalt_Iron_Cage/2282557
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A cyanide-bridged decanuclear [Co6Fe4] cluster was synthesized by a one-pot reaction, and the magnetic properties and electronic configuration were investigated. The complex displayed thermally controlled electron-transfer-coupled spin transition (ETCST) behavior between CoIII low-spin–NC–FeII low-spin and CoII high-spin–NC–FeIII low-spin states, as confirmed by single-crystal X-ray, magnetic, and Mössbauer analyses.
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2014-06-16
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