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Synthesis of Functionalized Fluorescent Indenes from Electron-Rich α-Aryl Ketonitriles

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Figshare2016-02-21 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Synthesis_of_Functionalized_Fluorescent_Indenes_from_Electron_Rich_Aryl_Ketonitriles/2529328
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A series of functionalized indenes bearing 1,3-dicyano groups were synthesized from electron-rich α-aryl ketonitriles in the presence of K3Fe­(CN)6 and NaOAc, possibly through tandem process involving dimerization, heterolytic cleavage of carbon–carbon bond, intermolecular coupling, and the subsequent intramolecular cyclization. The 2-arylindene compounds obtained possess good fluorescent properties.
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2016-02-21
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