Synthesis of Functionalized Fluorescent Indenes from Electron-Rich α-Aryl Ketonitriles
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A series of functionalized indenes bearing 1,3-dicyano groups were synthesized from electron-rich α-aryl ketonitriles in the presence of K3Fe(CN)6 and NaOAc, possibly through tandem process involving dimerization, heterolytic cleavage of carbon–carbon bond, intermolecular coupling, and the subsequent intramolecular cyclization. The 2-arylindene compounds obtained possess good fluorescent properties.
创建时间:
2016-02-21



