Synthesis of 2‑Azapyrenes and Their Photophysical and Electrochemical Properties
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https://figshare.com/articles/dataset/Synthesis_of_2_Azapyrenes_and_Their_Photophysical_and_Electrochemical_Properties/12935052
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A series of 5,7,9-substituted 2-azapyrenes were synthesized for the first time. The synthesis relies on Brønsted acid promoted benzannulation of alkyne precursors prepared by palladium-catalyzed cross-coupling reactions. The synthetic strategy is efficient and the scope covers a variety of functional groups. The electrochemical behavior and photophysical properties of the products were investigated by UV–vis and fluorescence spectroscopy, cyclic voltammetry, and DFT calculations.
创建时间：
2020-09-04
