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Iron-Catalyzed Intermolecular Hydrothiolation of Internal Alkynes with Thiosalicylic Acids, and Sequential Intramolecular Cyclization Reaction

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https://figshare.com/articles/dataset/Iron-Catalyzed_Intermolecular_Hydrothiolation_of_Internal_Alkynes_with_Thiosalicylic_Acids_and_Sequential_Intramolecular_Cyclization_Reaction/5282980
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资源简介:
We demonstrate the iron-catalyzed intermolecular coupling of internal alkynes and thiosalicylic acid derivatives. The reaction was effectively catalyzed by the Fe­(acac)2/1,10-phenanthroline catalyst in toluene/HFIP (hexafluoro­isopropyl alcohol) as the reaction solvent and afforded several types of 1,3-oxathiine derivatives in moderate to high yields through the intermolecular hydrothiolation and sequential intramolecular cyclization.
创建时间:
2017-08-07
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