Cobalt-Catalyzed Borylation of Aryl Halides and Pseudohalides
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https://figshare.com/articles/dataset/Cobalt_Catalyzed_Borylation_of_Aryl_Halides_and_Pseudohalides/3141919
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资源简介:
We report the first Co-catalyzed
borylation of aryl halides and
pseudohalides with bis(pinacolato)diboron (B2pin2). The synthesis of two new Co(II) complexes of oxazolinylferrocenylphosphine
ligands is described. Upon activation with LiMe, the Co complex catalyzes
the borylation reactions of aryl bromides, iodides, sulfonates, arenediazonium
salts, and even aryl chlorides under mild conditions, providing the
borylated products in excellent to moderate yields and with high functional
group tolerance.
创建时间:
2016-05-17



